Solar power accounts for about 2% of U.S. electricity, but it could become more widespread if it were cheaper to generate this electricity and make it readily available on cloudy days and at nighttime.
Developments in this research are important steps for putting solar heat-to-electricity generation in direct cost competition with fossil fuels, which generate more than 60% of electricity in the U.S.
Solar panel systems installed on farms and on rooftops are commonly used to generate electricity from the sun and already store energy for later use using batteries, but concentrated solar power plants can offer large-scale energy storage at a lower cost.
“Since storing solar energy as heat is already cheaper than storing energy via batteries, the next step is reducing the cost of generating electricity from the sun’s heat,” said Kenneth Sandhage, Purdue’s Reilly Professor of Materials Engineering.
There are only 11 concentrated solar power plants in the U.S., but the cost of producing electricity using these plants has dropped by more than 50% since 2010. Purdue researchers are working to reduce concentrated solar power costs even further to compete with fossil fuels.
Seeking solutions from seawater
To make it cheaper for concentrated solar power plants to produce electricity, the turbines of these plants need to operate at much higher temperatures. Turbines currently operate at a peak temperature of about 1,022 degrees Fahrenheit.
By operating the turbines at 1,382 degrees Fahrenheit or higher, a concentrated solar power plant could convert heat energy to electricity more efficiently. This also calls for enabling low-cost storage of solar heat at higher temperatures so that the plants can produce electricity 24 hours a day and respond quickly to surges in electrical demand.
Concentrated solar power plants can store energy from the sun by heating molten salts, but currently used molten nitrate salts would degrade at 1,382 degrees Fahrenheit. Sandhage and other researchers in the field have been turning to seawater for chloride-based salts that can stay stable enough at higher temperatures.
But seawater-derived molten chlorides, such as magnesium chloride-potassium chloride-bearing salts that researchers have examined so far, degrade by oxidation in ambient air at 1,382 degrees Fahrenheit.
In a study published in Materials, Sandhage’s research group predicted and demonstrated that a different sea-water-derived molten salt, a calcium chloride-sodium chloride composition, is highly resistant to oxidation in ambient air at 1,382 degrees Fahrenheit.
Sandhage’s research group also developed a way to make nickel corrosion-resistant so that it can better contain a molten salt such as the calcium chloride-sodium chloride composition.
“We have identified and demonstrated a salt that is stable and plentiful, and we have a containment strategy for holding the salt for extended times to store the energy for use when the sun isn’t shining,” Sandhage said.
Turning up the heat, one step at a time
To keep lowering the costs of generating electricity from concentrated solar power plants, other steps in the electricity generation process also need to handle higher temperatures.
One of those steps is the transfer of heat from a molten salt to a high-pressure working fluid through devices called heat exchangers. Upon heating, the working fluid expands and spins the turbine for generating electricity.
Compact, cost-effective heat exchangers are typically made of stainless steel alloys that would become too soft for use at 1,382 degrees Fahrenheit with a high-pressure working fluid.
In 2018, Sandhage and his collaborators published a paper in Nature revealing how heat exchangers made of a ceramic-metal composite material would be capable of withstanding the higher temperatures and pressures needed for generating electricity more efficiently. Purdue researchers invented this composite-based heat exchanger using materials that had been successfully tested at over 4,000 degrees Fahrenheit in solid-fuel rocket nozzles.
Molten salt and heat exchangers that can handle the heat are just two pieces of the puzzle. Other researchers in the field, for example, are making improvements to receivers—metal tubing carrying the molten salt to be heated by sunlight—and the mirrors that concentrate sunlight.
“If you want to run the whole system hotter, you can’t have a weak link anywhere in the chain,” Sandhage said.
And in some respects, temperatures need to be lower. Despite the advantages of the calcium chloride-sodium chloride composition, this salt melts at higher temperatures than currently used molten nitrate salts. Sandhage’s research group is working on tweaking the molten chloride salt composition to melt at lower temperatures while still remaining stable at high temperatures.
“Ultimately, continued developments will allow for large-scale penetration of renewable solar energy into the electricity grid,” Sandhage said. “This would mean dramatic reductions in man-made carbon dioxide emissions from electricity production.”